According to Markownikoff's rule,
when hydrogen chloride adds to an unsymmetrical alkene, the hydrogen of HX
attaches to:
(1) Carbon with least number of
hydrogens
(2) Carbon with most number of
hydrogens
(3) Carbon at the end of the
molecule
(4) Carbon in the middle of the
molecule
7.
Which fraction of the petroleum
corresponds to kerosene oil?
(1) 12% Cr, 1% Ni
(2) 2% Cr, 3% C
(3) 10% Ni, 2% Mn
(4) 8% Cr, 5% Mn
13.
Presence of halogens is organic
compounds is detected by:
(1)
Iodoform test
(2)
Silver nitrate test
(3)
Millon's test
(4)
Beilstein's test
14.
Number of ions present in K3[Fe(CN)6]
are:
(1) 2
(2) 3
(3) 4
(4) 10
15.
During the extraction of copper from
chalcopyrites, the matter obtained is mainly.
(1) Cuprous sulphide
(2) Cuprous oxide
(3) Mixture of cuprous oxide and
sulphide
(4) Copper metal
16.
Potassium metasulphite used as a
food preservative is:
(1) A positive catalyst
(2) A negative catalyst
(3) A homogeneous catalyst
(4) A heterogeneous catalyst
17.`
Highest pH (14) is given by:
(1) IN HCI
(2) IN NaOH
(3) 0.1M NaOH
(4) IM H2SO4
18.
The free energy change due to a
reaction is zero when:
(1) The reactants are completely
consumed
(2) The system is at equilibrium
(3) A catalyst is added
(4) The reactants are
initially mixed
19.
For the reaction CI2(g) +
2 NO (g) ® 2 NOCI (g) doubling the
concentration of both reactants increases the rate by a factor of eight. If
only the concentration of CI2 is doubled, the rate increases by a
factor of two, The order of the reaction with respect to NO is:
(1) 1
(2) 2
(3) 0.5
(4) 3
20.
In the Daniel cell constructed in
the laboratory, the voltage observed was 0.9 V instead of 1.1 V of the
standard cell. A possible explanation is:
(1) [Zn2+] > [Cu2+]
(2) [Zn2+] < [Cu2+]
(3) The Zn electrode has twice the
surface of Cu electrode
(4) Mole ratio of Zn2+ :
Cu2+ is 2 :1
21.
The compound which does not leave
any residue on heating is:
Usually ionic compounds are soluble
in polar solvents and covalent compounds is non-polar solvents. However
covalent compounds dissolve in polar solvents like water due to:
(1) H-bond formation
(2) Proton transfer reaction
(3) Their behaviour as Lewis acids
(4) Any of the above
27.
Nitrogen atom has three unpaired
electrons because of:
In an FCC metal the atoms are in
physical contact along
(1) Body diagonal
(2) Face diagonal
(3)
Cube edge
(4) All the above directions
41.
A real gas tends to behave more
ideally at:
(1) High temperature and high
pressure
(2) High temperature and low
pressure
(3) Low temperature and high
pressure
(4) Low temperature and low pressure
42.
The half-life of a radioactive
isotope is 1.5 hours. If its initial mass is 32 grams, the mass that remains
after 6 hours is
(1) 2g
(2) 4g
(3) 8g
(4) 16g
`
43.
The shape of atomic orbitals is
given by
(1) Principal quantum number
(2) Subsidiary quantum number
(3) Magnetic quantum number
(4) Spin quantum number
44.
High purity hydrogen is produced by
the reaction
(1)
(2)
(3)
(4)
45.
H2O2 is
(1) An oxidizing agent
(2) A reducing agent
(3) Both an oxidizing and a reducing
agent
(4) Neither oxidizing nor reducing
agent
46.
Calculate
DH0 for the reaction H2O
(l) ®H2(g) +O2(g)
given 2 H2 (g) +O2(g)
®2 H2O (l) H=-571.6 kJ